A Guide to Problems in Modern Electrochemistry: 1: Ionics by Maria E. Gamboa-Adelco, Robert J. Gale (auth.)

By Maria E. Gamboa-Adelco, Robert J. Gale (auth.)

It has been consistently an incentive for college kids to discover even if his/her efforts to unravel routines provide right effects, or to discover assistance for difficulties that he/she reveals tougher. those are the most purposes for the looks of the current publication. As a part of the textbook ModernElectrochemistry 1: Ionics, A advisor to difficulties in ModernElectrochemistry: half 1: Ionics compiles a number of the suggestions to the routines and difficulties awarded within the textual content, in addition to many new problems.

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Extra resources for A Guide to Problems in Modern Electrochemistry: 1: Ionics

Example text

3, and that of pure water 78. What is the dielectric constant of a solution 30% of this amine? (GamboaAldeco) Answer: The relationship between dielectric constant and concentration is a linear one (cf. Eq. 99) 43 ION-SOLVENT INTERACTIONS = 0, & = &0 = 78. 95. 30)] = 56. 33 For a given water molecule, what is the maximum number of hydrogen bonds that can be form with other neighboring water molecules? Are these hydrogen bonds identical in bonding nature? Explain. If there were a difference in bonding nature for these hydrogen bonds, how would you differentiate them experimentally?

A reasonable value for I would be of the order of the radius or diameter of the considered ion. Thus, in general, the value of I can be taken to be of the order of 100 nm. 81) =2DT where D is the diffusion coefficient, k is the rate constant for diffusion and T is the mean jump time to cover the mean jump distance (seconds per jump). 0X10 - 5 cms - l ) In the same way, the radius of the r ion is 216 pm. 83) 38 CHAPTER 2 The Li+ ion, being such a small ion, can move much faster than the much bigger iodide ion, spending less time (small r) in jumping the mean jump distance.

Refer to the drawing in Fig. 2 for angles and distances in the water molecule. (b) Knowing the dipole moment of water, write an equation expressing it in terms of the fractional charge on either end of the dipole, /. and the distance between the center of charge and the atomic nucleus, x. , 1201) between 8-0-8, and draw the corresponding dipole moment vector. (Cf. 24 in the textbook) (Mussini) 44 CHAPTER 2 o H H Fig. 2. Angles and distances in the water molecule. Answer: (a) The dipole moment is given by f-l = qd .

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